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Sunday, May 11, 2008

 

CENTER OF GRAVITY
By Rony V. Diaz
Green chemistry

 
EVERY time Earth Day is celebrated, the chemical industry takes a beating.

This year, opprobrium was heaped on plastics and agricultural chemicals.

A legislator announced that she would sponsor a bill that would proscribe all plastics, not knowing perhaps that plastics is an all-purpose name for a wide range of products that are ubiquitous as well as indispensable.

Agro-chemicals include not only fertilizers, herbicides and pesticides but also preparations that make chicken, pig and fish farming possible and at the same time protect human health.

Organic farming sounds fine but I doubt if it can sustain large-scale food production.

This is not to say that the chemical industry should be allowed free rein to do what it pleases. Some of its products have been found to be harmful to the environment and toxic to human beings. We should be on guard but selective and rational in what to prohibit.

It was not always like this. There was a time when industrial chemistry was seen as a boon and not a bane.

Remember the 1935 slogan of Du Pont? It promised to deliver “Better Things for Better Living Through Chemistry.” Du Pont has since lowered its voice.

Industrial chemistry became a social and economic force when Fritz Haber, the German physical chemist, solved the problem of making ammonia from ambient nitrogen. His discovery was heaven-sent. Germany was on the brink of famine because its access to Chilean nitrates, the main raw material for fertilizer, was cut by the war. But it took Carl Bosch, a chemical engineer, to industrialize Haber’s discovery. Synthetic ammonia provided Germany not only with the fertilizer it needed to grow food but also the material to make explosives. Industrial chemistry has always been double-edged.

In the 1920s, the petrochemical industry grew when chemical engineers at the Massachusetts Institute of Technology (MIT) devised quantitative tools to analyze fractional distillations and the Dow Chemical Co. perfected continuous automatic control technology.

However, the substitution of a cheaper synthetic product for a natural one could be said to have begun in 1861 when Alexander Parkes, an English chemist, patented a malleable material from nitrocellulose and wood naptha that he named Parkesine. It was a commercial failure until he and Daniel Spill put on the market a concoction of nitrocellulose, alcohol, camphor and castor oil that they called Xylonite. Combs, shirt collars, knife handles and other devices were manufactured in large quantities from Xylonite.

Thereafter, products with trademarks like nylon and freon that have become common nouns—all based on petroleum—quickly found favor in the marketplace.

With the spread of the internal combustion engine, gasoline, kerosene, solvents, lubricants, coolants, anti-freeze and synthetic polymer products to make artificial rubber followed in quick succession.

Public perception of the chemical industry turned negative when it was found that lead tetraethyl, the anti-knock additive in gasoline, and chloroflurocar­bons in refrigerators and air­conditioners were harmful to both humans and to the ozone layer that protected the Earth from ultraviolet rays.

But it was Rachel Carson’s Silent Spring in 1962 that decisively turned public opinion against synthetic chemicals particularly against DDT. It was banned in most countries with disastrous consequences for malaria control and eradication.

To restore the chemical industry to its former status as a force for good, American chemical companies launched the Responsibility Care Program under which they agreed “constantly and continuously to improve performance—no matter what base they start from—through the implementation of a series of codes of performance objectives addressing community awareness and emergency response, pollution prevention, process safety, employee health and safety, distribution and product stewardship . . .” Only firms that abide by these standards can join the American Chemical Manufacturers’ Association.

Chemical technology is neither good nor bad in itself. However, it has unforeseen consequences especially when applied on a massive scale.

Perhaps the solution is to revive the chemurgic movement that was begun in the US in the 1930s by Francis Garvan and William J. Hale. Chemurgic’s aim was to use surplus farm produce as the raw materials of the chemical industry. These are cellulose, vegetable oil and alcohol.

With biofuels, especially cellulosic ethanol and jatropha diesel fuel, sugarcane, sugar beets and plant cellulose to make biodegradable plastics, we are already on the chemurgic track.

Nobody knows when these products will become economically viable but instead of excoriating chemistry we should encourage more organic chemists to look deeper into fermentation and catalysis as the basic processes to produce the substitutes for the petroleum-and coal-based products that we use almost mindlessly today.

The answer is green chemistry.

opinion@manilatimes.net

   
 

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